Using perovskite–silicon tandem solar cells to improve efficiency

A solar-cell module that mitigates cell-to-module losses has been developed by researchers from the King Abdullah University of Science and Technology (KAUST), following a rethink of the module’s optical design and how it should be stacked. Researchers around the world are trying to improve the efficiency of solar cells; however, using these devices in the real world represents an extra challenge, as solar cells need to be incorporated into modules that can protect the sensitive materials from harsh environments. These modules can reduce the power conversion efficiency, thus losing the performance gains achieved in the laboratory.

Lujia Xu, Stefaan De Wolf and their fellow KAUST researchers have constructed a more efficient solar-cell module with an enhanced optical design. The solar cells used by the team were made of a combination of two light-absorbing semiconductors: one silicon and the other made from the perovskite material. Silicon is an established material in solar cell manufacture and while perovskites are an emerging material, adding a thin layer on top of the silicon has been shown to improve performance with an acceptable increase in cost. These perovskite–silicon tandem solar cells have previously exhibited efficiencies in optical-to-electrical power conversion, as high as 30%, with theoretical modelling indicating that it could go as high as 45%.

When the researchers put their tandem solar cells into a module, they found that the efficiency dropped from 28.9% to 25.7%. Their module was made by sandwiching the solar cells between two glass sheets, with the inside filled with thermoplastic polyurethane to encapsulate the solar cells. The researchers believed the reduction in efficiency is due to a refractive index mismatch after the introduction of glass and the polyurethane directly on solar cells without cell-to-module optimisation, resulting in increased reflection of the incoming light. As a result, the researchers decided to reduce this front reflection loss by an optical redesign of the module through refractive-index engineering. By removing a film of magnesium fluoride from the top of the cell to the top of the front glass, the researchers reduced the refractive index mismatch, thus achieving efficient light in-coupling.

“This simple optimisation effectively enables the highest short circuit current density — related to the maximum current that can be drawn from the device — that is reported in the literature for monolithic perovskite/silicon tandem solar modules, resulting in a power conversion efficiency increase from 25.7% to 26.2%. We now hope to explore how different materials and texturing the material surface could reduce the current losses from cells to modules even further,” Xu said.

The research findings were published in ASC Energy Letters.

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