Perovskite/CIS tandem solar cell breakthrough

An international team of researchers has produced perovskite/CIS tandem solar cells with an efficiency of nearly 25% — the highest known value achieved thus far with this technology. The result has been published in the journal ACS Energy Letters.

Perovskites are innovative materials with a special crystal structure. With an efficiency that is now comparable to that of the long-established silicon solar cells, researchers worldwide are working to get perovskite photovoltaic technology ready for practical applications. The more electricity they generate per unit of surface area, the more attractive solar cells are for consumers.

The efficiency of solar cells can be increased by stacking two or more cells; if each of the stacked solar cells is especially efficient at absorbing light from a different part of the solar spectrum, inherent losses can be reduced and efficiency boosted. Thanks to their versatility, perovskite solar cells make outstanding components for such tandems. Tandem solar cells using perovskites and silicon have now reached an efficiency level of over 29% — considerably higher than that of individual cells made of perovskite (25.7%) or silicon (26.7%).

Combining perovskites with other materials such as copper-indium-diselenide (CIS) or copper-indium-gallium-diselenide (CIGS) promises further benefits. Such combinations will make it possible to produce light and flexible tandem solar cells that can be installed not only on buildings but also on vehicles and portable equipment. Such solar cells could even be folded or rolled up for storage and extended when needed, for example on blinds or awnings, to provide shade and generate electricity at the same time.

Researchers headed by Dr Marco A Ruiz-Preciado and Ulrich W Paetzold from the Karlsruhe Institute of Technology (KIT) have produced perovskite/CIS tandem solar cells with a maximum efficiency of 24.9% (23.5% certified) — the highest reported efficiency for this technology and the first high efficiency level reached at all with a nearly gallium-free copper-indium diselenide solar cell in a tandem, according to Ruiz-Preciado. Reducing the amount of gallium results in a narrow band gap of approximately 1 eV, which is very close to the ideal value of 0.96 eV for the lower solar cell in a tandem.

The band gap is a material characteristic that determines the part of the solar spectrum that a solar cell can absorb to generate electricity. In a monolithic tandem solar cell, the band gaps must be such that the two cells can produce similar currents to achieve maximum efficiency. If the lower cell’s band gap changes, the upper cell’s band gap has to be adjusted to the change, and vice versa.

To adjust the band gap for efficient tandem integration, perovskites with high bromine content are usually used. However, this often leads to voltage drops and phase instability. Since the KIT researchers and their partners use CIS solar cells with a narrow band gap at the base of their tandems, they can produce their upper cells using perovskites with low bromine content, which results in cells that are more stable and efficient.

“Our study demonstrates the potential of perovskite/CIS tandem solar cells and establishes the foundation for future development to make further improvements in their efficiency,” Paetzold said.

Image credit: Marco A Ruiz-Preciado, KIT.

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