Low-energy process developed for high-performance solar cells

Finding reliable, eco-friendly power sources is crucial as our world grapples with increasing energy needs and the urgent call to combat climate change. Solar energy offers one solution, with scientists devising ever more efficient materials for capturing sunlight.

Perovskite solar cells have emerged as a promising alternative to conventional, silicon solar cells, boasting a number of advantages. But processing the material has been a complicated affair. Now, researchers at UC Santa Barbara have developed a method to make high-quality perovskite films at room temperature. The team’s innovation not only simplified the production process but also increased the material’s efficiency from under 20 to 24.4%. The details appear in the journal Joule.

Perovskite is a class of materials characterised by its specific crystal structure, exemplified by the mineral of the same name. Solar cells made from this material boast many advantages compared to silicon-based solar cells. They’re lightweight and flexible, and can be applied as a spray or printed like ink. Perovskite solar cell production also has the potential for a smaller carbon footprint than silicon photovoltaics, which require high temperatures and a cleanroom environment.

That said, producing these cells involves high-temperature annealing and tricky post-treatment steps, significantly slowing fabrication and making it hard to incorporate them into everyday items. These factors impede perovskite’s adoption in large-scale manufacturing and make it less environmentally friendly.

By fine-tuning the material’s chemical composition, the authors developed a perovskite ink that created high-quality films much more effectively. “Our method follows the same procedures as the conventional one, except for omitting the two most time-consuming steps: thermal annealing and post-treatment,” said co-lead author Ahra Yi, a postdoctoral researcher at UC Santa Barbara. The simpler fabrication technique also meshes better with standard manufacturing processes and reduces the overall energy use, which lowers its carbon dioxide emissions.

What’s more, the new material outperformed cells made using the high-temperature process. “Our optimised perovskite solar cell achieved a remarkable efficiency of 24.4%,” said co-lead author and UCSB doctoral student Sangmin Chae, “surpassing previous limits, which were below 20% for room-temperature processed devices.”

The new procedure is also extremely gentle. To demonstrate this, the team prepared a perovskite layer on fresh leaves, a feat that was impossible with the previous, high-temperature process. “We thought this choice would be both eye-catching and symbolic, since solar cells mimic the photosynthetic process in leaves,” Yi said.

A thin perovskite film coats a fresh leaf. Image credit: Ahra Yi and Sangmin Chae et al.

This versatility opens up a wide range of possible applications. It’s well suited for flexible indoor and outdoor energy generation. “With our approach, we can now contemplate the development of high-efficiency solar cells with free-form designs capable of powering the ever-increasing array of wearable electronics, sensors, displays, security cameras, Internet of Things (IoT) devices, et cetera,” said senior author, Professor Thuc-Quyen Nguyen, director of the UCSB Centre for Polymers & Organic Solids.

This is a modified version of a news item published by the University of California, Santa Barbara. The original version of the news item can be accessed here.

Top image credit: iStock.com/gorodenkoff