Insights into the dielectric properties of strontium titanate


Monday, 20 June, 2022

Insights into the dielectric properties of strontium titanate

US and UK researchers have solved a longstanding mystery surrounding strontium titanate — an unusual metal oxide that can be an insulator, a semiconductor or a metal. Published in the journal PNAS, their research provides insight for future applications of this material to electronic devices and data storage.

When an insulator like strontium titanate is placed between oppositely charged metal plates, the electric field between the plates causes the negatively charged electrons and the positive nuclei to line up in the direction of the field. This orderly lining up of electrons and nuclei is resisted by thermal vibrations, and the degree of order is measured by a fundamental quantity called the dielectric constant. At low temperature, where the thermal vibrations are weak, the dielectric constant is larger.

In semiconductors, the dielectric constant plays an important role by providing effective ‘screening’, or protection, of the conducting electrons from other charged defects in the material. For applications in electronic devices, it is critical to have a large dielectric constant.

High-quality, centimetre-size samples of strontium titanate exhibit a measured low-temperature dielectric constant of 22,000, which is quite large, and encouraging for applications. But most applications in computers and other devices would call for thin films. Despite an enormous effort by many researchers using diverse methods to grow thin films, only a modest dielectric constant of 100–1000 has been achieved in thin films of strontium titanate.

In thin films, which can be just a few atomic layers thick, the interface between the film and substrate, or the film and the next layer up, can play an important role. University of Minnesota Associate Professor Bharat Jalan theorised that these ‘buried’ interfaces might be masking the true dielectric constant of strontium titanate. By carefully accounting for this masking effect, Jalan and his students discovered that the true dielectric constant of their strontium titanate films exceeds 25,000 — the highest ever measured for this material.

The findings by Jalan and his team provide critical insight into the role of interfaces between an insulator and a metal as found in capacitor structures ubiquitous in modern technology, even when both the metal and the insulator are derived from the same material. They have also resolved a longstanding issue concerning the low dielectric constants in strontium titanate films through defect and interface control.

“Semiconductors are among the most important materials used in modern technology,” Jalan said. “While much is known about conventional semiconductors such as silicon and gallium arsenide, there are several unsolved mysteries surrounding oxide semiconductors like strontium titanate.”

“These results build on a remarkable record of success for the method of film growth, known as hybrid molecular beam epitaxy, discovered by Jalan,” said study co-author Professor Richard James, also from Minnesota. “The quality of the films from Jalan’s group is truly exceptional.”

Image credit: Jalan Group, University of Minnesota.

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