Nanowires under tension could enable ultrafast transistors

Novel concepts based on semiconductor nanowires are expected to make transistors in microelectronic circuits better and more efficient. Electron mobility plays a key role in this: the faster electrons can accelerate in these tiny wires, the faster a transistor can switch and the less energy it requires.

A team of researchers from the Helmholtz-Zentrum Dresden-Rossendorf (HZDR), Technische Universität Dresden and NaMLab has now demonstrated that electron mobility in nanowires is remarkably enhanced when the shell places the wire core under tensile strain. This phenomenon, published in the journal Nature Communications, offers novel opportunities for the development of ultrafast transistors.

Nanowires have a unique property: they can sustain very high elastic strains without damaging the crystal structure of the material. Yet the materials themselves are not unusual; gallium arsenide, for example, is widely used in industrial manufacturing, and is known to have a high intrinsic electron mobility.

To further enhance this mobility, the Dresden researchers produced nanowires consisting of a gallium arsenide core and an indium aluminium arsenide shell. The different chemical ingredients result in the crystal structures in the shell and the core having slightly different lattice spacings. This causes the shell to exert a high mechanical strain on the much thinner core. The gallium arsenide in the core changes its electronic properties.

“We influence the effective mass of electrons in the core,” said Dr Emmanouil Dimakis, a scientist at the HZDR’s Institute of Ion Beam Physics and Materials Research. “The electrons become lighter, so to speak, which makes them more mobile.”

What started out as a theoretical prediction has now been proven experimentally. As explained by Dr Dimakis, “We knew that the electrons in the core ought to be even more mobile in the tensile-strained crystal structure, but what we did not know was the extent to which the wire shell would affect electron mobility in the core. The core is extremely thin, allowing electrons to interact with the shell and be scattered by it.”

A series of measurements and tests demonstrated this effect. Despite interaction with the shell, electrons in the core of the wires under investigation moved approximately 30% faster at room temperature than electrons in comparable nanowires that were strain-free or in bulk gallium arsenide.

Revealing the core

The researchers measured electron mobility by applying contactless optical spectroscopy: using an optical laser pulse, they set electrons free inside the material. The scientists selected the light-pulse energy such that the shell seems practically transparent to the light, and free electrons are only produced in the wire core. Subsequent high-frequency terahertz pulses caused the free electrons to oscillate.

“We practically give the electrons a kick and they start oscillating in the wire,” explained PD Dr Alexej Pashkin, who optimised the measurements for testing the core-shell nanowires with his team at the HZDR. Comparing the results with models reveals how the electrons move: the higher their speed and the fewer obstacles they encounter, the longer the oscillation lasts.

“This is actually a standard technique,” Dr Pashkin said. “But this time we did not measure the whole wire — comprising the core and the shell — but only the tiny core. This was a new challenge for us. The core accounts for around 1% of the material. In other words, we excite about a hundred times fewer electrons and get a signal that is a hundred times weaker.”

Consequently, the choice of sample was also a critical step. A typical sample contains an average of around 20,000 to 100,000 nanowires on a piece of substrate measuring roughly 1 mm². If the wires are spaced even closer together on the sample, an undesirable effect can occur: neighbouring wires interact with each other, creating a signal similar to that of a single, thicker wire, and distorting the measurements. If this effect is not detected, the electron velocity obtained is too low. To rule out such interference, the research team carried out additional modelling as well as a series of measurements for nanowires with different densities.

With the researchers’ achievement looking particularly promising for ultrafast transistors, the team’s next step will be to develop the first prototypes based on the studied nanowires and to test their suitability for use. To do this, they intend to apply, test and enhance metallic contacts on the nanowires, as well as testing the doping of nanowires with silicon and optimising manufacturing processes.

Image caption: Terahertz spectroscopy measurements showed that the strained core of semiconductor nanowires can host fast-moving electrons, a concept that could be employed for a new generation of nano-transistors. Image credit: HZDR/Juniks.

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